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  • Glass Science: Reports From R.M. Hovhannisyan Et Al Highlight Recent

    GLASS SCIENCE; REPORTS FROM R.M. HOVHANNISYAN ET AL HIGHLIGHT RECENT RESEARCH IN GLASS SCIENCE

    Science Letter
    July 22, 2008

    According to recent research from Yerevan, Armenia, "An insufficient
    level of investigations on barium titanium borate system both
    in crystalline and in glassy states has stimulated the present
    research. The phase diagram of the ternary BaO-TiO2-B2O3, system
    have been constructed revealing six ternary eutectic and seven
    peritectic compositions in the ternary system and two new binary
    eutectic compositions in the BaO-B2O3 corrected system."

    "The phase diagram in the pseudo-binary barium borate-barium titanate
    system is revised. The new crystalline 2BaO.TiO2.B2O3 compound is
    revealed at the same glass composition crystallisation. It melted
    incongruently at 940 degrees C with the formation of melt and
    barium titanate. The x-ray characteristics of 2BaO.TiO2B2O3 are
    reported. It has orthorhombic or tetragonal crystal symmetry and
    lattice constants (A): a-11.84, b-9.64, c-18.24, Z=21. The influence
    of various methods of melt casting on the glass forming ability in
    the ternary BaO-TiO2-B2O3 system is investigated. The expanded glass
    formation area changes from stable glass forming barium tetraborate
    up to binary dibarium borate and tip to barium dititanate," wrote
    R.M. Hovhannisyan and colleagues (see also Glass Science).

    The researchers concluded: "A clear correlation between glass forming
    ability and eutectic areas is revealed in the investigated system."

    Hovhannisyan and colleagues published their study in Physics
    and Chemistry of Glasses - European Journal of Glass Science and
    Technology Part B (Mutual influence of barium borates, titanates
    and borontitanates on phase diagram and glass formation in the
    BaO-TiO2-B2O3 system. Physics and Chemistry of Glasses - European
    Journal of Glass Science and Technology Part B, 2008;49(2):63-67).

    For additional information, contact R.M. Hovhannisyan, Institute
    Materials Science Agh, 17 Charents St., Yerevan 375025, Armenia.

    Publisher contact information for the Physics and Chemistry of Glasses
    - European Journal of Glass Science and Technology Part B is: Society
    Glass Technology, Unit 9, Twelve O Clock Court, 21 Attercliffe Rd.,
    Sheffield S4 7WW, S Yorkshire, England.
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